Demand analysis of zirconia oxygen analyzers in the new energy industry

Release time: 2025-02-13


Lithium-ion battery production involves steps such as electrode preparation, coating, drying, winding, filling, and sealing. The drying process requires controlling the moisture and oxygen in the environment, especially during the drying of electrode materials and before filling. Because moisture and oxygen affect the stability of the electrolyte and battery performance, inert gas protection in the production environment, such as nitrogen or argon, requires oxygen content monitoring. A zirconia oxygen analyzer is used to monitor the oxygen concentration in the environment in real-time, ensuring it is at an extremely low level to prevent battery material oxidation.

In addition, during sintering or high-temperature processing, such as the sintering of cathode materials, the furnace atmosphere needs to be controlled, and oxygen content also needs to be monitored. Zirconia sensors can withstand high temperatures and are suitable for this environment. Also, the filling workshop needs to be in a drying room, and oxygen content control is equally critical to prevent electrolyte decomposition.

Then, why does the lithium battery industry need this instrument, and not other types of oxygen analyzers? The advantages of zirconia are its high precision, fast response, and high-temperature resistance, making it suitable for harsh industrial environments. At the same time, the expansion of lithium battery production scale and higher requirements for quality control are driving the demand for this instrument.

Considering industry development trends, such as the oxygen sensitivity of high-nickel cathode materials and the need for stricter atmosphere control in solid-state battery production, these will increase the demand for zirconia oxygen analyzers. In addition, improved environmental protection and energy consumption requirements mean that companies need to optimize processes and reduce defect rates, which also requires precise oxygen monitoring.

The demand analysis for zirconia oxygen analyzers in the lithium battery production industry is based on the following aspects:

1. Oxygen control needs in lithium battery production

Lithium battery production requires extremely strict control of oxygen content, with the main applications including:

  • Electrode material preparation The sintering process of cathode materials (such as ternary materials and lithium iron phosphate) must be carried out in a low-oxygen or oxygen-free environment to prevent material oxidation or structural damage.
  • Drying process The drying process after electrode coating requires controlling environmental humidity and oxygen content to avoid the reaction of active substances with water/oxygen.
  • Filling and sealing The electrolyte is sensitive to water and oxygen. The filling workshop needs to maintain an inert gas (such as nitrogen) environment, and the oxygen content needs to be below the ppm level.
  • Battery assembly Winding and stacking processes must avoid contact between metallic lithium or electrode materials and oxygen to prevent side reactions.

Zirconia oxygen analyzers ensure that the production environment meets process requirements by monitoring oxygen concentration in real-time, guaranteeing battery performance and safety.

2. Technical advantages of zirconia oxygen analyzers

Compared to electrochemical or infrared oxygen analyzers, zirconia sensors are more competitive in the lithium battery industry:

  • High-temperature adaptability It can be directly used for atmosphere monitoring in high-temperature sintering furnaces (above 800°C).
  • High precision and fast response The detection accuracy can reach ±0.1% O The response time is short (millisecond level), suitable for dynamic process control.
  • Strong stability Corrosion-resistant and pollution-resistant, suitable for complex industrial environments (such as workshops containing organic solvents or dust).
  • Low maintenance cost No consumables, long service life, suitable for continuous production needs.

3. Industry driving factors

  • Energy density improvement needs High-nickel ternary and silicon-based anode materials are sensitive to oxygen and require stricter atmosphere control.
  • Solid-state battery development Solid-state electrolyte production requires higher water and oxygen control (dew point <-40°C, O <1ppm).
  • Quality control and consistency Large-scale production of power batteries needs to reduce batch differences, and oxygen content monitoring is the key to process standardization.
  • Environmental protection and energy consumption optimization Precise control of inert gas usage reduces production costs (such as nitrogen consumption) and carbon emissions.

4. Market demand analysis

  • Incremental demand The global expansion of lithium battery production capacity (especially in China, Europe, and North America) is driving equipment procurement. It is estimated that the global lithium battery drying/filling equipment market size will exceed US$5 billion in 2025, and the demand for oxygen analyzers as supporting equipment will grow simultaneously.
  • Replacement demand Traditional oxygen analyzers (such as paramagnetic) are gradually being replaced by zirconia in high-temperature and high-precision scenarios.
  • Customized demand Manufacturers need to provide explosion-proof "TFEX-8", miniaturized "VDK-800", or solutions integrated with MES systems to adapt to different production line designs.

5. Competitive landscape and challenges

  • International brands dominate Japanese Yokogawa, Swiss ABB, German Siemens, etc., occupy the high-end market, and domestic substitution is gradually progressing (such as Anhui Tianfen, Vidoc Analytical Instruments, etc.).
  • Technical challenges It is necessary to solve the drift problem of sensors under extreme conditions (such as high humidity and organic vapor).
  • Cost Pressure Small and medium-sized battery factories are sensitive to equipment prices and need to balance performance and cost.

6. Future Trends and Suggestions

  • Intelligent Integration Combine IoT technology to achieve real-time monitoring of oxygen content data and automatic process adjustment.
  • Material Innovation Develop zirconia probes resistant to sulfide/fluoride corrosion to adapt to new electrolyte systems.
  • Localized Service Provide quick calibration and maintenance services to enhance customer loyalty.
  • Policy Promotion Countries are tightening battery safety standards (such as UN38.3, GB 38031), mandating oxygen control in the production process, further stimulating demand.

Conclusion

The demand for zirconia oxygen analyzers in the lithium battery industry will continue to grow, driven by the application of high energy density materials, production process upgrades, and global capacity expansion. Anhui Tianfen will focus on high-precision, high-temperature, and customized solutions, while leveraging localized services and cost control advantages to seize market share.

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EXNFZRO®2 Explosion-proof Zirconia Oxygen Analyzer Significance of Measuring Oxygen Content with Zirconia Analyzer Flue gas oxygen content is one of the important monitoring parameters for boiler operation and an important basis for reflecting the completeness of combustion equipment and boiler operation. Its value is related to factors such as boiler structure, type and nature of fuel, boiler load, operating air supply conditions, and equipment sealing conditions. The smaller the oxygen content, i.e., the smaller the excess air coefficient, the more it indicates increased heat loss due to incomplete chemical combustion and mechanical incomplete combustion; the larger the oxygen content, i.e., the larger the excess air coefficient, the more it indicates excessive air supply. Excess air causes a drop in furnace temperature, which not only affects combustion but also carries away a large amount of heat and dust, increasing the calculated concentration of pollutant emissions. At the same time, a large air volume also increases the power consumption of flue gas exhaust. Controlling flue gas oxygen content is very important for controlling the combustion process and achieving safe, efficient, and low-pollution emissions. Application Scope The zirconia oxygen analyzer is an instrument used to monitor and control the oxygen concentration in combustion gases, boilers, and industrial furnaces. It is widely used in coal-fired power plants, gas boilers, waste incineration boilers, hazardous waste disposal incinerators, petrochemical cracking furnaces, metallurgical industry blast furnace hot blast stoves, oxygen-enriched combustion air pipelines, sintering furnaces, heating furnaces, heat treatment furnaces, metal material annealing furnaces, air separation oxygen production, food industry, cement kilns in the building materials industry, glass kilns, inert gas protection furnaces in the semiconductor industry, electrode material production furnaces in the lithium battery industry, and waste lithium battery recycling. It helps save energy and can also reduce CO2, SOX, and NOx emissions by controlling complete combustion, contributing to environmental protection, preventing global warming, and reducing air pollution. Anhui Tianfen Instrument Co., Ltd. is a manufacturer of zirconia analyzers, providing products for steel mills, chemical plants, power plants, waste power plants, and more. Their product range includes TKFX-ZOA zirconia analyzers, ZO-2000 desktop zirconia analyzers, MKFB-400-A/H explosion-proof zirconia analyzers, ZOA-300B zirconia analyzers, ZO-FIIB explosion-proof zirconia oxygen analyzers, CY-ZC, CY-ZDA zirconia analyzers, OXT3000 series zirconia oxygen content analyzers, integrated oxygen analyzers, corrosion-resistant zirconia analyzers, YB-88G zirconia oxygen analyzers, OXT1000 series zirconia analyzers, TKZO-5 zirconia analyzers, NFZRO2-5 zirconia analyzers, ZR402G zirconia oxygen analyzers, CE-2C, CE-2D zirconia analyzers, ZFK8R zirconia analyzers, hot blast stove zirconia analyzers for steel mills, special zirconia analyzers for hazardous waste, MK-400-A-FHC corrosion-resistant zirconia analyzers, abrasion-resistant zirconia analyzers, EXFZZRO2-88 explosion-proof zirconia analyzers, FZZRO2-5 zirconia oxygen analyzers, NFZO-05 high-temperature extraction zirconia analyzers, YB-88GJ-ZW zirconia analyzers, abrasion-resistant zirconia analyzers, oxygen analyzers, trace oxygen analyzers, steel mill zirconia analyzers, waterproof zirconia analyzers. Oxygen analyzers include the OAM-800 oxygen analyzer (zirconia) and the OAM-802 explosion-proof oxygen analyzer (zirconia), as well as the BOA-807 series (integrated) and BOA-807-R (split) series specifically for waste power plant boilers. Oxygen analyzers measure the oxygen concentration in flue gas and other non-combustible gases during combustion. Tianfen oxygen analyzers include the OAM-800 oxygen analyzer (zirconia) and the OAM-802 explosion-proof oxygen analyzer (zirconia). The standard oxygen analyzers include the integrated OAM-800 and the split OAM-800-R. They use a direct insertion online measurement method, can display measurement data and fault information on-site, and feature high accuracy, fast measurement, and low maintenance. The OAM-800 series features zirconia sensors with nano-coatings and various abrasion-resistant protective tubes. The explosion-proof oxygen analyzers include the integrated OAM-802 and the split OAM-802-R. These are PCEC-certified explosion-proof products suitable for boilers, heating furnaces, incinerators, converters, and other explosion-proof environments.
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